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Kamalesh Pal Amitava Mukherjee Md. Motin Seikh Parthasarathi Bera Arup Gayen 《Ceramics International》2021,47(10):14798-14808
Synthesis of nanocrystalline pristine and Mn-doped calcium copper titanate quadruple perovskites, CaCu3?xMnxTi4?xMnxO12 (x = 0, 0.5, and 1.0) by modified citrate solution combustion method has been reported. Powder X-ray diffraction patterns attest the phase purity of the perovskite materials. Average particle sizes of all the materials obtained from the Scherrer's formula are in the range of 55–70 nm. The specific surface areas for all the perovskites obtained from BET isotherms are found to be low as expected for the condensed oxide systems and fall in the range of 13–17 m2 g?1. Transmission electron microscopy studies show a reduction in particle size of CaCu3Ti4O12 with increase in Mn doping. Ca and Ti are present in +2 and +4 oxidation states in all the materials as demonstrated by X-ray photoelectron spectroscopy analyses. Cu2+ gets reduced in CaCu3Ti4O12 with higher Mn content. Mn is observed to be present only in +3 oxidation state. All the materials have been examined to be active in CO oxidation as well as H2 production from methanol steam reforming. CaCu3Ti4O12 with ~14 at.% Mn is found to show best catalytic activities among these materials. A comprehensive analysis of the catalytic activities of these perovskites toward CO oxidation and H2 production from MSR reveal the cooperative activity of copper-manganese in the doped perovskites and it is more effective at lower manganese content. 相似文献
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基于网络零售平台与制造商的合作广告实践,运用Stackelberg博弈理论研究了平台交叉销售效应及合作广告引导作用对O2O供应链合作广告决策的影响,并通过数值算例对参与合作广告计划前后渠道成员的决策变量均衡结果和利润进行对比分析,研究发现平台交叉销售效应是影响网络零售平台合作广告计划制定和实施的关键因素,只有当其达到一定水平时,制造商才拥有参与网络零售平台合作广告计划的资格;在一定条件时,合作广告计划能够实现制造商和网络零售平台利润的提升;当平台交叉销售效应较大时,网络零售平台获得的利润大于制造商。 相似文献
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In this article, we introduce a new bi-directional dual-relay selection strategy with its bit error rate (BER) performance analysis. During the first step of the proposed strategy, two relays out of a set of N relay-nodes are selected in a way to optimize the system performance in terms of BER, based on the suggested algorithm which checks if the selected relays using the max-min criterion are the best ones. In the second step, the chosen relay-nodes perform an orthogonal space-time coding scheme using the two-phase relaying protocol to establish a bi-directional communication between the communicating terminals, leading to a significant improvement in the achievable coding and diversity gain. To further improve the overall system performance, the selected relay-nodes apply also a digital network coding scheme. Furthermore, this paper discusses the analytical approximation of the BER performance of the proposed strategy, where we prove that the analytical results match almost perfectly the simulated ones. Finally, our simulation results show that the proposed strategy outperforms the current state-of-the-art ones. 相似文献
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Danilo Tardioli Luis Riazuelo Domenico Sicignano Carlos Rizzo Francisco Lera Jos L. Villarroel Luis Montano 《野外机器人技术杂志》2019,36(6):1074-1101
The work reported in this article describes the research advances and the lessons learned by the Robotics, Perception and Real‐Time group over a decade of research in the field of ground robotics in confined environments. This study has primarily focused on localization, navigation, and communications in tunnel‐like environments. As will be discussed, this type of environment presents several special characteristics that often make well‐established techniques fail. The aim is to share, in an open way, the experience, errors, and successes of this group with the robotics community so that those that work in such environments can avoid (some of) the errors made. At the very least, these findings can be readily taken into account when designing a solution, without needing to sift through the technical details found in the papers cited within this text. 相似文献
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本文即针对当前智能变电站中的故障诊断问题展开分析,主要以继电保护二次回路故障检测为主,就诊断检测系统进行阐述,总结了能够针对各种故障问题进行检测手段,意在能够借此提升变电站的智能化发展水平。 相似文献
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一种大型复杂构件加工新模式及新装备探讨 总被引:3,自引:3,他引:0
大型复杂构件是航空航天、能源、船舶等领域装备的核心结构件,此类构件通常具有尺寸大、形状复杂、刚性弱等特点。传统“分体离线加工-在线检测”模式存在工艺不稳定、过程复杂、柔性差、周期长等问题,以龙门式多轴数控机床加工为代表的“包容式”加工模式,难以适应大型复杂构件的高效高质量加工制造需求。提出一种基于移动式和吸附式机器人的多机协同原位加工新模式,通过多机器人系统自主寻位、精确定位加工与加工质量原位检测,实现大型复杂构件多安装面并行铣削、制孔与打磨等作业。多机器人系统包括移动式混联机器人、吸附式并联机器人、移动式串联铣削机器人、移动式双臂加工机器人和移动式打磨机器人。构建多机协同原位加工模式,需要揭示多机器人协同原位加工行为与大型弱刚性结构件质量控制的交互机理,面临着本体、测量、工艺和集成四个方面的挑战,需要设计高灵活、高刚度的移动式和吸附式加工机器人,解决移动机器人自主准确寻位和超大结构件原位高精检测难题,攻克加工变形误差在线补偿和振动抑制技术,通过集成实现多机协同高效高精加工,为大型复杂构件的高效高质量制造提供创新技术及装备,并实现此类构件制造核心技术及装备自主可控。 相似文献
9.
Thummaros Rugthum Gang Tao 《International Journal of Adaptive Control and Signal Processing》2021,35(9):1916-1940
This article develops a new framework of adaptive actuator failure compensation control for cooperative manipulator systems with parameter uncertainties in addition to actuator failures, and designs and analyzes effective actuator failure compensation schemes for such robotic systems. The new adaptive control design uses an integration of multiple individual failure compensators and direct adaptation to handle various types of uncertainties in such robotic systems. The design can also be used for concurrent actuator failure cases, to expand the capability of adaptive actuator failure compensation. With a complete proof and performance analysis, it is shown that the proposed control scheme guarantees the desired closed-loop stability and asymptotic output tracking, despite actuator failures whose patterns, time instants and values are all unknown. Simulation results of a benchmark cooperative manipulator system are presented to verify the desired control performance of the system with both typical constant and square-wave actuator failure signals. 相似文献
10.
在传统的三段式继电保护离线整定的定值性能分析过程中,常因定值选择不合理而导致定值计算准确度低。为此,在确定影响分支系数大小的因素的基础上,将分支系数看作为预计算变量,建立故障分析模型,计算三段式继电保护过程后备保护定值;设定三段式继电保护离线整定定值优化约束条件,采用滑膜变结构控制方法设定控制策略,结合惩罚函数的形式将约束条件添加到目标函数中,将定值性能分析问题转化为无约束优化问题,实现基于滑模变结构控制的三段式继电保护离线整定的定值性能分析。实验结果表明,相比于传统方法,该方法的定值准确度更高,定值性能更好。 相似文献